
TY  - JOUR
A1  - Colton, R 
A1  - Farthing, RH 
A1  - McCormick, MJ 
T1  - Carbonyl halides of the Group VIII transition metals. VI. Compounds of palladium(I)
JF  - Australian Journal of Chemistry
JO  - Aust. J. Chem.
Y1  - 1973
VL  - 26
IS  - 12
SP  - 2607
EP  - 2614
KW  - 
UR  - https://doi.org/10.1071/CH9732607 
N2  - The carbonyl halides Pd(CO)Cl and Pd(CO)Br have been prepared by the action of carbon monoxide on palladium(II) halides in aqueous hydrohalic acid solution. In addition, the caesium salts CsPd(CO)Cl2 and CsPd(CO)Br2, and the rubidium salt RbPd(CO)Cl2, were also isolated. The corresponding iodo complexes could not be prepared.     By direct interaction of the carbonyl halides with bis(diphenylarsino)methane (dam) the compounds [Pd(dam)X]2 (X = Cl, Br) were prepared. The formulation of all these complexes as compounds of palladium(I) was confirmed on the basis of various physical measurements. 
ER  -

