
TY  - JOUR
A1  - Fee, WW 
A1  - Pulsford, JD 
A1  - Vowles, PD 
T1  - Copper(II)-promoted solvolyses of nickel(II) complexes. II. Tridentate and tetradentate Schiff base ligands containing remote substituents
JF  - Australian Journal of Chemistry
JO  - Aust. J. Chem.
Y1  - 1973
VL  - 26
IS  - 7
SP  - 1459
EP  - 1473
KW  - 
UR  - https://doi.org/10.1071/CH9731459 
N2  - The kinetics of copper(II)-promoted solvolyses of two series of nickel(II) complexes containing polydentate Schiff bases with various remote substituents, in dimethyl sulphoxide (dmso), are discussed from the viewpoints of rate constants and of enthalpies and entropies of activation. Appearance of an isokinetic relation for the tridentate (ONS donors) reactants may indicate a common mechanism operative within this reactant series. Rate constants appear related to &#963;p values in such a way that a dissociative mechanism appears important for the tridentate reactants, while characterization in terms of associative behaviour is indicated for the tetradentates. 
ER  -

