
TY  - JOUR
A1  - Murray, KS 
A1  - Simm, GR 
A1  - West, BO 
T1  - Vanadium(III) chloro and bromo complexes with tetradentate Schiff base ligands
JF  - Australian Journal of Chemistry
JO  - Aust. J. Chem.
Y1  - 1973
VL  - 26
IS  - 5
SP  - 991
EP  - 996
KW  - 
UR  - https://doi.org/10.1071/CH9730991 
N2  - Vanadium(III) Schiff base chelates of the types V(chel)Cl,py (chel = saen, saph) and V(saen)Cl,py2 have been synthesized by allowing VCl3 and the ligand to react in pyridine solutions. The bromo derivatives V(saen)Br,py and V(saph)Br,py2 can be obtained by LiBr substitution. The magnetic and spectral properties of the complexes are consistent with tetragonally distorted octahedral structures, though the &#956;eff value for V(saen)Cl,py is slightly lower than expected and difficult to explain with certainty. 
ER  -

