
TY  - JOUR
A1  - Goodwin, HA 
A1  - Smith, FE 
A1  - Konig, E 
A1  - Ritter, G 
T1  - METAL COMPLEXES OF 1,10-PHENANTHROLINE DERIVATIVES V.* BIS-LIGAND IRON(II) COMPLEXES OF 1 ,10-PHENANTHROLINE-2-CARBOTHIOAMIDE
JF  - Australian Journal of Chemistry
JO  - Aust. J. Chem.
Y1  - 1973
VL  - 26
IS  - 3
SP  - 521
EP  - 528
KW  - 
UR  - https://doi.org/10.1071/CH9730521 
N2  - The preparation of 1,10-phenanthroline-2-carbothioamidea nd its bis-ligand complexes of iron(II) is described. The ligand produces a strong field and the magnetic and Mossbauer effect data for the complexes indicate that in these the metal atom has a 1A1 ground state. The ligand can coordinate as a neutral or anionic tridentate, producing either cationic or neutral complexes. The electronic spectra of the cationic complexes are typical for the iron(II)-bis-terimine system and show intense charge-transfer absorption. Infrared data indicate that the sulphur atom of the thioamido group is coordinated. 
ER  -

