
TY  - JOUR
A1  - Subramanian, MS 
A1  - Pai, SA 
A1  - Manchanda, VK 
T1  - Complexes of uranyl &#946;-diketonates with sulphoxides
JF  - Australian Journal of Chemistry
JO  - Aust. J. Chem.
Y1  - 1973
VL  - 26
IS  - 1
SP  - 85
EP  - 89
KW  - 
UR  - https://doi.org/10.1071/CH9730085 
N2  - The proton magnetic resonance spectra of the synergistic complexes of uranyl &#946;-diketonates with dihexyl sulphoxide as the neutral donor give a multiplet consisting of eight lines for the terminal methylene group protons adjacent to the sulphur atom of the sulphoxide and a triplet for the &#946;-methylene protons. This conforms to an ABX2 pattern arising as a result of nonequivalence of the two protons of the terminal methylene group as a result of steric hindrance to free rotation about the C-S bond. The presence of such restricted rotation has been adduced as evidence for a direct donor-metal bond. 
ER  -

