
TY  - JOUR
A1  - Coutts, RSP 
A1  - Martin, RL 
A1  - Wailes, PC 
T1  - Monocyclopentadieny1titanium(III) compounds. III. Complexes of oxygencontaining ligands
JF  - Australian Journal of Chemistry
JO  - Aust. J. Chem.
Y1  - 1973
VL  - 26
IS  - 1
SP  - 47
EP  - 55
KW  - 
UR  - https://doi.org/10.1071/CH9730047 
N2  - Complexes of the type cpTiX2,nL [where cp = &#960;-cyclopentadienyl; X = Cl or Br; n = 1 when L = 1,2-dimethoxyethane (dme); n = 2 when L = ethanol (EtOH), or methanol (MeOH)] have been prepared. Various physical properties, including magnetism and electronic spectra, have been measured and interpreted on the basis of six-coordinate titanium(III) atoms. The magnetic moments of all complexes approximate to the spin-only value.     Reactions with dioxan did not result in the formation of stoichiometric complexes, while &#946;-diketones caused rupture of the cp-Ti bonds as well as the halide-titanium bonds giving known tris-&#946;- diketonates of titanium(III). 
ER  -

