
%0 Journal Article
%A Coutts, RSP 
%A Martin, RL 
%A Wailes, PC 
%T Monocyclopentadieny1titanium(III) compounds. III. Complexes of oxygencontaining ligands
%J Australian Journal of Chemistry
%D 1973/01/01
%V 26
%N 1
%P 47-55
%K 
%R https://doi.org/10.1071/CH9730047
%U https://www.publish.csiro.au/paper/CH9730047 
%X Complexes of the type cpTiX2,nL [where cp = &#960;-cyclopentadienyl; X = Cl or Br; n = 1 when L = 1,2-dimethoxyethane (dme); n = 2 when L = ethanol (EtOH), or methanol (MeOH)] have been prepared. Various physical properties, including magnetism and electronic spectra, have been measured and interpreted on the basis of six-coordinate titanium(III) atoms. The magnetic moments of all complexes approximate to the spin-only value.     Reactions with dioxan did not result in the formation of stoichiometric complexes, while &#946;-diketones caused rupture of the cp-Ti bonds as well as the halide-titanium bonds giving known tris-&#946;- diketonates of titanium(III). 
