
TY  - JOUR
A1  - James, K 
A1  - Angyal, SJ 
T1  - New synthesis of 1-deoxyhexuloses
JF  - Australian Journal of Chemistry
JO  - Aust. J. Chem.
Y1  - 1972
VL  - 25
IS  - 9
SP  - 1967
EP  - 1977
KW  - 
UR  - https://doi.org/10.1071/CH9721967 
N2  - By displacement of a nitrobenzene-p-sulphonyloxy group by iodide ion from position 1 of 2,3:4,6-di-O-isopropylidene-&#945;-L-sorbofuranose and 2,3:4,5-di-O-iso-propylidene-&#946;-D-fructopyranose, and subsequent hydrogenolysis, 1-deoxy-L-sorbose and 1-deoxy-D-fructose, respectively, have been synthesized. Inversion by oxidation with ruthenium tetroxide, and subsequent reduction, provided new syntheses of D-tagatose and 1-deoxy-L-psicose. The N.M.R. spectrum shows that the aqueous solution of 1-deoxy-D-fructose contains a considerable proportion of the keto form; this proportion increases with increasing temperature. 
ER  -

