
TY  - JOUR
A1  - Czernohorsky, JH 
A1  - Richards, KE 
A1  - Wright, GJ 
T1  - The Mills-Nixon effect. III. Detritiation of veratrol, 1,3-benzodioxole, and 1,4-benzodioxan
JF  - Australian Journal of Chemistry
JO  - Aust. J. Chem.
Y1  - 1972
VL  - 25
IS  - 7
SP  - 1459
EP  - 1464
KW  - 
UR  - https://doi.org/10.1071/CH9721459 
N2  - The rates of detritiation of [3-T]- and [4-T]-veratrol, [4-T]- and [5-T]-1,3-benzodioxole, and [5-T]- and [6-T]-1,4-benzodioxan have been measured at 30º in anhydrous trifluoroacetic acid. The observed order of reactivities can be explained in terms of a balance of strain and hybridization effects imposed by the fused ether rings, and differences in the extent of Ar-O delocalization among the three substrates. 
ER  -

