
%0 Journal Article
%A Coutts, RSP 
%A Martin, RL 
%A Wailes, PC 
%T Monocyclopentadienyltitanium(III) compounds. II. Complexes of nitrogen containing ligands
%J Australian Journal of Chemistry
%D 1972/07/01
%V 25
%N 7
%P 1401-1409
%K 
%R https://doi.org/10.1071/CH9721401
%U https://www.publish.csiro.au/paper/CH9721401 
%X The complexes cpTiCl2, bipy, cpTiCl2,phm, cpTiCl2,2py, and cpTiCl2,2pic (bipy = bipyridyl, phm = o-phenylenediamine, py = pyridine, pic = &#945;-picolylamine, cp = &#960;-cyclopentadienyl) have been prepared by allowing the appropriate nitrogen base to react with cpTiCl2. Spectroscopic, magnetic, and conductivity data are consistent with either non-ionic, six-coordinate dimeric species with pseudooctahedral symmetry or five-coordinate monomeric species. A complex of the type cpTiCl2,1.5en (en = ethylenediamine) was also formed. Possible structures are discussed. 
