
%0 Journal Article
%A Cambie, RC 
%A Mathai, KP 
%A Missen, AW 
%T Chemistry of the Podocarpaceae. XL. Conversion of methyl 12-Hydroxypodocarpa-8,11,13-trien-19-oate into Methyl 13-hydroxypodocarpa-8,11,13-trien-19-oate
%J Australian Journal of Chemistry
%D 1972/06/01
%V 25
%N 6
%P 1253-1269
%K 
%R https://doi.org/10.1071/CH9721253
%U https://www.publish.csiro.au/paper/CH9721253 
%X Methods for the conversion of methyl (+)-12-hydroxypodocarpa-8,11,13- trien-19-oate (7) into the synthetically more useful compound methyl (+)-13-methoxypodocarpa-8,11,13-trien-19-oate (8) have been investigated. In the most favourable case, the transformation has been effected in c. 57% yield by a five-stage sequence involving hydrogenolysis of the 13-amino-12-tosylate (31) with Raney nickel. 
