
TY  - JOUR
A1  - Dubicki, L 
T1  - The electronic spectrum of binuclear copper acetate monohydrate
JF  - Australian Journal of Chemistry
JO  - Aust. J. Chem.
Y1  - 1972
VL  - 25
IS  - 6
SP  - 1141
EP  - 1149
KW  - 
UR  - https://doi.org/10.1071/CH9721141 
N2  - The near-ultraviolet spectrum of copper(11) acetate monohydrate consists of at least two bands centred at 360 and 325 nm, and polarized parallel and perpendicular to the copper-copper axis, respectively. From the temperature dependence of intensity the two bands are identified as singlet-singlet transitions. Their polarizations and intensities are consistent with the charge transfer assignments,   lAlg &#8594; lA2u [b2u(py) &#8594; bIg(x2-y2)] and lAlg &#8594; lEu [eg(px) &#8594; bu2(x2-y2)], where b2u(py) and eg(px) are nonbonding ligand molecular orbitals composed of out-of-plane and in-plane oxygen 2p-orbitals, respectively. 
ER  -

