
TY  - JOUR
A1  - Baker, JR 
A1  - Watson, ID 
A1  - Williamson, AG 
T1  - Hydrogen bonding in chloroform and ether mixtures
JF  - Australian Journal of Chemistry
JO  - Aust. J. Chem.
Y1  - 1971
VL  - 24
IS  - 10
SP  - 2047
EP  - 2051
KW  - 
UR  - https://doi.org/10.1071/CH9712047 
N2  - The hydrogen bonding between chloroform and di-n-alkyl ethers has been studied over the temperature range -50°C to + 50°C using proton magnetic resonance. The measurements of chemical shift have been interpreted in terms of the formation of a 1 : 1 complex between the chloroform and the ether. Mole fraction association constants in the range 1-5 were found. The enthalpies of formation of the complexes deduced from the temperature coefficients of the equilibrium constants varied from -8 kJ mol-1 to -11.7 kJ mol-1. 
ER  -

