
TY  - JOUR
A1  - Bloom, H 
A1  - Anthony, RG 
T1  - Mass spectrometry of the vapours over PbBr<sub>2</sub>+MBr mixtures (M = Na, K, Rb, Cs)
JF  - Australian Journal of Chemistry
JO  - Aust. J. Chem.
Y1  - 1971
VL  - 24
IS  - 10
SP  - 2001
EP  - 2004
KW  - 
UR  - https://doi.org/10.1071/CH9712001 
N2  - A mass spectrometric study of vapours above molten PbBr2+MBr mixtures has revealed the existence of vapour species of general formula MPbBr3 (M = Na, K, Rb, Cs). Second-law enthalpies of formation of these complexes were found to be in the range -39 to -44 kcal/mol; entropies of formation are estimated between -20 to -21 e.u. It is believed that these complex molecules have a bipyramidal structure. 
ER  -

