
TY  - JOUR
A1  - Campbell, JR 
A1  - Pross, A 
A1  - Sternhell, S 
T1  - Preparation and chemistry of some 1-Iodo-1-phenylpropenes
JF  - Australian Journal of Chemistry
JO  - Aust. J. Chem.
Y1  - 1971
VL  - 24
IS  - 7
SP  - 1425
EP  - 1436
KW  - 
UR  - https://doi.org/10.1071/CH9711425 
N2  - The oxidation of eight aryl alkyl hydrazones with iodine in the presence of triethylamine gave mixtures of 1-iodo-1-arylpropenes and ketones in yields of 36-73% and 19-43% respectively. Further evidence is presented in favour of an iodocarbonium ion intermediate for this reaction. Aspects of the photochemistry of 1-iodo-1-arylpropenes and their reaction with naphthylsodium are reported. The product distribution of the naphthylsodium reactions is consistent with an intermediate sp2-hybridized (?bent?) 1-arylpropenyl radical. 
ER  -

