
%0 Journal Article
%A West, RJ 
%A Lincoln, SF 
%T The exchange of acetonitrile on iron(II) in acetonitrile solvent. A nitrogen-14 nuclear magnetic resonance study
%J Australian Journal of Chemistry
%D 1971/06/01
%V 24
%N 6
%P 1169-1175
%K 
%R https://doi.org/10.1071/CH9711169C
%U https://www.publish.csiro.au/paper/CH9711169C 
%X A 14N n.m.r. study of the exchange reaction Fe(CH3CN)62+ &#9586; CH3CN in CH3CN solvent is reported. The value for k 1 (25&#176;C) from the rate law R = 6k1[Fe(CH3CN)62+] is (5.5 &#177; 0.8) &#215; 105 s-1, &#916;H&#8225; = 9.7 &#177; 0.7 kcal mol-1, &#916;S&#8225; = 0.3 &#177; 2.2 cal mol-1 K-1, and A/h = 5.0 &#215; 106 Hz. These data are compared with those of related systems. 
