
%0 Journal Article
%A Sutton, GJ 
%T Some studies in inorganic complexes. XXVI. Complexes of 6-Methyl-2-thioamidopyridine
%J Australian Journal of Chemistry
%D 1971/05/01
%V 24
%N 5
%P 919-924
%K 
%R https://doi.org/10.1071/CH9710919
%U https://www.publish.csiro.au/paper/CH9710919 
%X Several complexes of the chelating ligand 6-methyl-2-thioamidopyridine have been prepared end studied. Infrared spectra indicate that the sulphur atom of the thioamido group is bonding in the complexes: [CoL2(H2O)2][ClO4]2, [NiL2Br2], [CuL2]I, [Ru2L4Cl2O]Cl2, [OsL2Cl2], [AuL][AuCl1], and [HgLI2] whereas nitrogen bonding occurs with [FeLCl3]2, [ZnL3][ClO4]2, [SnLI4], and the deprotonated species [In(L-H)3]. Copper(II) was reduced to copper(I), e.g. [CuL2][CuBr2]. Studies in the visible spectrum, magnetic measurements, and conductances in both nitrobenzene and dimethylformamide were also made. 
