
TY  - JOUR
A1  - Miller, IJ 
T1  - Ring strain and the negative pole. IV. Relationships dependent on localized electric field
JF  - Australian Journal of Chemistry
JO  - Aust. J. Chem.
Y1  - 1971
VL  - 24
IS  - 3
SP  - 457
EP  - 464
KW  - 
UR  - https://doi.org/10.1071/CH9710457 
N2  - The acidity, infrared stretching frequency, and bond length of a substituent atom on a strained ring is linearly dependent on the contribution of the ring atom to the negative pole as previously defined. Bond strengths are similarly, but non-linearly, proportional. A qualitative explanation for the stability of the molecules of the Group V elements is offered. An explanation for the Schmidt rule is also offered, and it is deduced that this rule should be applicable to any bond &#945;,&#946; to a strained alicyclic small ring. 
ER  -

