
TY  - JOUR
A1  - Black, DSC 
A1  - Lane, MJ 
T1  - Metal template reactions. IV. The attempted dimerization of &#945;,&#969; amino aldehydes around nickel(II) ions
JF  - Australian Journal of Chemistry
JO  - Aust. J. Chem.
Y1  - 1970
VL  - 23
IS  - 10
SP  - 2055
EP  - 2065
KW  - 
UR  - https://doi.org/10.1071/CH9702055 
N2  - The dimerization of certain &#945;,w amino aldehydes around a nickel(11) ion-a potentially useful procedure for the preparation of macrocyclic nickel(11) complexes-could not be achieved. Hydrogenation of 2-formyl-2'-nitrodiphenylamine and several of its derivatives, with or without the presence of nickel(11) ions, in all cases yielded 10,11-dihydro-5H dibenzo[b,f][1,4]diazepine.   &#945;,w Amino acetals have been prepared by reactions of 2-minobenzaldehyde and 2-nitrobenzalclehyde respectively with 2-amino-1,l-diethoxyethane, followed by reduction in the latter case, but these could not be converted into macrocyclic products. 
ER  -

