
%0 Journal Article
%A Stals, J 
%T The chemistry of aliphatic unconjugated nitramines. III. Thermal, electrophilic, and nucleophilic reactions
%J Australian Journal of Chemistry
%D 1969/12/01
%V 22
%N 12
%P 2515-2526
%K 
%R https://doi.org/10.1071/CH9692515
%U https://www.publish.csiro.au/paper/CH9692515 
%X The VESCF(BJ)-MO electronic bond energies, charge distributions, bond orders, free valencies, and frontier orbital charges, when used as reactivity indices, provide a surprisingly good account of the thermal decomposition and of the electrophilic and nucleophilic substitution reactions of nitramide and primary and secondary aliphatic nitramines. A good account of the chemistry of RDX and HMX is also given by the calculated parameters for s- and as-N,N-dimethylnitramines. 
