
TY  - JOUR
A1  - McAskill, NA 
T1  - Energy dependence of ion-molecule reactions. II. Methyl chloride
JF  - Australian Journal of Chemistry
JO  - Aust. J. Chem.
Y1  - 1969
VL  - 22
IS  - 11
SP  - 2275
EP  - 2285
KW  - 
UR  - https://doi.org/10.1071/CH9692275 
N2  - The ion-molecule reactions of ions in methyl chloride were studied in the gas phase at source pressures of up to 120 &#956; in a mass spectrometer using ions having exit energies which ranged from 0.2 to 2.0 eV. The ions produced by secondary processes included CH4Cl+, CH2Cl+, and C2H6Cl+. The rate constant for the reaction of CH3Cl+ was found to be independent of the ion energy in the energy range studied. A theoretical rate constant which is independent of the ion energy was also derived for reactions between ions and polar molecules. Negative ion spectra were briefly examined. 
ER  -

