
TY  - JOUR
A1  - Cox, BG 
A1  - McTigue, PT 
T1  - Addition compounds of aldehydes
JF  - Australian Journal of Chemistry
JO  - Aust. J. Chem.
Y1  - 1969
VL  - 22
IS  - 8
SP  - 1637
EP  - 1647
KW  - 
UR  - https://doi.org/10.1071/CH9691637 
N2  - Equilibrium constants at 298°K have been measured spectrophotometrically for the following reactions in water:        (i) Hydrogen-bonded addition of the aldehyde hydrates ethane, propane-, and butane-1,1-diols to the anions chloride, acetate, hydrogen carbonate, hydrogen phosphate, and dihydrogen phosphate.        (ii) Nucleophilic addition of imidazole to the aldehydes ethanal, propanal, and butanal.        (iii) Hydration (to 1,1-diols) of ethanal, propanal, 2- methylpropanal, and butanal.     P.m.r. and kinetic evidence is presented to support the assumed nature of the equilibria discussed. 
ER  -

