
TY  - JOUR
A1  - Matthews, DB 
T1  - The potential dependence and upper limit of electrochemical charge transfer rates
JF  - Australian Journal of Chemistry
JO  - Aust. J. Chem.
Y1  - 1969
VL  - 22
IS  - 7
SP  - 1349
EP  - 1353
KW  - 
UR  - https://doi.org/10.1071/CH9691349 
N2  - A theory is developed to predict the potential dependence at high rates, and the upper limit, of electrochemical charge transfer reactions. The theory utilizes a constant symmetry factor and shows how the properties of the overlapping electron distribution functions produce a non-linear dependence of log(rate) on electrode potential, and hence a dependence of the effective symmetry factor on electrode potential. 
ER  -

