
%0 Journal Article
%A Matthews, DB 
%T The potential dependence and upper limit of electrochemical charge transfer rates
%J Australian Journal of Chemistry
%D 1969/07/01
%V 22
%N 7
%P 1349-1353
%K 
%R https://doi.org/10.1071/CH9691349
%U https://www.publish.csiro.au/paper/CH9691349 
%X A theory is developed to predict the potential dependence at high rates, and the upper limit, of electrochemical charge transfer reactions. The theory utilizes a constant symmetry factor and shows how the properties of the overlapping electron distribution functions produce a non-linear dependence of log(rate) on electrode potential, and hence a dependence of the effective symmetry factor on electrode potential. 
