
TY  - JOUR
A1  - Bowie, JH 
A1  - Hoffmann, PJ 
T1  - Electron impact studies. XLVIII. Specific hydrogen-rearrangements in the mass spectra of <I>ortho</I>-alkoxyanils
JF  - Australian Journal of Chemistry
JO  - Aust. J. Chem.
Y1  - 1969
VL  - 22
IS  - 6
SP  - 1219
EP  - 1227
KW  - 
UR  - https://doi.org/10.1071/CH9691219 
N2  - The mass spectra of anils with ortho-alkoxyl substituents in the aromatic ring derived from the aldehyde contain pronounced peaks prod- uced by C=N bond cleavage accompanied by one and/or two hydrogen transfers to the nitrogen-containing fragment. Deuterium-labelling studies show that the hydrogen atoms involved are those attached to the &#945;-carbon (&#945; to oxygen) of the alkoxyl group. The extent of the hydrogen rearrangements may be altered by the addition of further substituents to the aromatic rings. 
ER  -

