
TY  - JOUR
A1  - Coutts, RSP 
A1  - Kautzner, B 
A1  - Wailes, PC 
T1  - Tetraphenylborate derivatives of titanium(III)
JF  - Australian Journal of Chemistry
JO  - Aust. J. Chem.
Y1  - 1969
VL  - 22
IS  - 6
SP  - 1137
EP  - 1141
KW  - 
UR  - https://doi.org/10.1071/CH9691137 
N2  - Three new titanium(III) compounds which incorporate solvent molecules have been prepared by replacing the chlorido ligand of cp2TiCl by the non-coordinating group BPh4-. The new compounds are formulated as [cp2Ti(H2O)3]2[BPh4]2, [cp2Ti(N&#8801;CCH3)2]BPh4, and [cp2Ti(py)2]BPh4. The methyl cyanide and pyridine complexes are monomeric and show the normal paramagnetic behaviour of isolated titanium(III) compounds, but the aquo derivative is dimeric with magnetic interaction between titanium atoms. 
ER  -

