
%0 Journal Article
%A Coutts, RSP 
%A Kautzner, B 
%A Wailes, PC 
%T Tetraphenylborate derivatives of titanium(III)
%J Australian Journal of Chemistry
%D 1969/06/01
%V 22
%N 6
%P 1137-1141
%K 
%R https://doi.org/10.1071/CH9691137
%U https://www.publish.csiro.au/paper/CH9691137 
%X Three new titanium(III) compounds which incorporate solvent molecules have been prepared by replacing the chlorido ligand of cp2TiCl by the non-coordinating group BPh4-. The new compounds are formulated as [cp2Ti(H2O)3]2[BPh4]2, [cp2Ti(N&#8801;CCH3)2]BPh4, and [cp2Ti(py)2]BPh4. The methyl cyanide and pyridine complexes are monomeric and show the normal paramagnetic behaviour of isolated titanium(III) compounds, but the aquo derivative is dimeric with magnetic interaction between titanium atoms. 
