
%0 Journal Article
%A Bowie, JH 
%A Duus, F 
%A Lawesson, S 
%A Larsson, FCV 
%A Madsen, J+ 
%T Electron impact studies. XL. Negative-ion mass spectra of organosulphur compounds : Thioglycollic acids and arylsulphinylamines
%J Australian Journal of Chemistry
%D 1969/01/01
%V 22
%N 1
%P 153-159
%K 
%R https://doi.org/10.1071/CH9690153
%U https://www.publish.csiro.au/paper/CH9690153 
%X The negative-ion mass spectra of thioglycollic esters and S- alkylthioglycollic acids exhibit ions produced by simple cleavage and/or cleavage with hydrogen rearrangement. Similar spectra of arylsulphinylamines show pronounced molecular ions together with simple cleavage fragments. No skeletal-rearrangement fragments are present in the negative-ion spectra, in marked contrast with those observed in the corresponding positive-ion spectra. 
