
TY  - JOUR
A1  - O'Conner, MJ 
A1  - West, BO 
T1  - N-Substituted salicylaldimine complexes of chromium(III)
JF  - Australian Journal of Chemistry
JO  - Aust. J. Chem.
Y1  - 1968
VL  - 21
IS  - 2
SP  - 369
EP  - 372
KW  - 
UR  - https://doi.org/10.1071/CH9680369 
N2  - Tris(salicylaldehydato)chromium(111) reacts readily with primary amines or ammonia to give complexes of the form Cr(sal-NR)3 where R = n-C3H9, i-C4H9, p-C6H4CH3, p-C6H4Br. The complexes are monomeric in benzene, and have magnetic moments in the range 3.77-3.81 B.M. at room temperature. Crystal field splitting energies have been obtained for the complexes from their spectra. Ethylenediamine reacts with the salicylaldehyde complex to give a cationic complex containing the tridentate ligand -0-C6H4-CH=NCH2CH2-NH2. 
ER  -

