
TY  - JOUR
A1  - Chia, PSK 
A1  - Livingstone, SE 
T1  - Sulphur-nitrogen chelating agents. V. Complexes of 2-Methyl-8-methylthioquinoline with some transition metals: The occurrence of tetrahedral complexes of cobalt(II), nickel(II), and copper(II)
JF  - Australian Journal of Chemistry
JO  - Aust. J. Chem.
Y1  - 1968
VL  - 21
IS  - 2
SP  - 339
EP  - 351
KW  - 
UR  - https://doi.org/10.1071/CH9680339 
N2  - Complexes of 2-methyl-8-methylthioquinoline (mmtq) have been obtained with cobalt(11), nicke1(11), palladium(11), platinum(11), copper(1), copper(11), silver(1), and gold(111). The 2-methyl group of mmtq causes severe steric hindrance to other ligands in a square plane. The complex AuCl3 mmtq contains five-coordinate gold(111).   Only one bis-chelated complex, Pd mrntq2(ClO4)2,H2O, was isolated and it is possible that the metal atom in this complex is five-coordinate also. The solid reflectance spectra of the compounds MX2 mmtq (M = Co, Ni, Cu; X = Cl, Br) and CoI2 mmtq indicate a pseudo-tetrahedral configuration about the metal atom in these complexes. 
ER  -

