
TY  - JOUR
A1  - Bloom, H 
A1  - Reinsborough, VC 
T1  - Cryoscopy in molten pyridinium chloride
JF  - Australian Journal of Chemistry
JO  - Aust. J. Chem.
Y1  - 1967
VL  - 20
IS  - 12
SP  - 2583
EP  - 2587
KW  - 
UR  - https://doi.org/10.1071/CH9672583 
N2  - The molal cryoscopic constant in molten pyridinium chloride (m.p. 146.0°) has been found to be 17.4° (subject to confirmation by calorimetry) and the cryoscopic heat of fusion, 2310±40 cal mole-1. In pyridinium chloride as a solvent, iodides appear to dissociate completely while bromides do not yield the expected depression possibly because of solid solution. Tetraalkylammonium and alkyl-pyridinium halides of high molecular weight are ideally dissociated in extremely dilute solution but with increasing concentration apparently form micelles. 
ER  -

