
TY  - JOUR
A1  - Buckingham, DA 
A1  - Durham, L 
A1  - Sargeson, AM 
T1  - Conformations, configurations, and proton reactions of colbalt(III) complexes
JF  - Australian Journal of Chemistry
JO  - Aust. J. Chem.
Y1  - 1967
VL  - 20
IS  - 2
SP  - 257
EP  - 280
KW  - 
UR  - https://doi.org/10.1071/CH9670257 
N2  - Proton magnetic resonance spectroscopy allows the cis and trans isomers of [CoX2 en2] complexes to be distinguished. Some information has been obtained concerning the rate of chelate conformational interchange for cobalt-ethylenediamine, propylenediamine, N-methylethylenediamine, and malonate rings. For [Co(amino acid)en2]2+ complexes the diastereoisomeric pairs can be differentiated and the relative rates of CH and NH proton exchange have been observed for a variety of chelate rings including cobalt-amino acid, acetylacetonato, ethylenediamine, and malonato. 
ER  -

