
TY  - JOUR
A1  - Curtis, NF 
A1  - Curtis, YM 
T1  - Some amine-thiocyanate complexes of nickel(II)
JF  - Australian Journal of Chemistry
JO  - Aust. J. Chem.
Y1  - 1966
VL  - 19
IS  - 8
SP  - 1423
EP  - 1430
KW  - 
UR  - https://doi.org/10.1071/CH9661423 
N2  - The preparation and properties of Ni(l,3-pn)2(NCS)2, Ni(trien)(NCS)2, Ni(tet a)(NCS)2, Ni(tet b)(NCS)2, Ni(dien)(NCS)2, Ni(dpt)(NCS)2, Ni(en)2NCSClO4, and Ni(trien)NCSClO4 are described (1,3-pn = 1,3-diaminopropane, trien = triethylenetetramine, tet a and tet b are isomeric hexamethylcyclotetradecanes, dien = diethylenetriamine, dpt = dipropylenetriamine, en = ethylenediamine). The first four compounds are normal N-bonded dithiocyanato derivatives, the dien and dpt derivatives have structures with one N-bonded terminal, and one bridging thiocyanate ion, and the thiocyanate perchlorate compounds have structures with a bridging thiocyanate ion. Magnetic susceptibilities (all &#956;eff c. 3.1 B.M.), infrared spectra (including that of N-deuterated Si(l,3-pn)2(NCS)2), reflectance spectra, and conductances in methanol and acetone are reported. 
ER  -

