
%0 Journal Article
%A Dalton, LK 
%T The preparation of Thiazolidine-2-thiones from N-alkylglucosylamines
%J Australian Journal of Chemistry
%D 1966/03/01
%V 19
%N 3
%P 445-450
%K 
%R https://doi.org/10.1071/CH9660445
%U https://www.publish.csiro.au/paper/CH9660445 
%X N-Alkylglucosylamines and carbon disulphide react to give 3-alkyl-5-hydroxy- 5-(D-arabino-tetrahydroxybutyl)thiazolidine-2-thiones (I), which dehydrate to the corresponding &#916;4-thiazolines, isolated only as tetraacetates. A thiazolidine-2-thione forms also from the action of carbon disulphide on 1-N-methylamino-1-deoxy-D-fructose.   l-Bromo-l-deoxy-2,3:4,5-di-O-isopropylidene-D-fructose is obtained by the action of dibromotriphenoxyphosphorane on 2,3:4,5-di-O-isopropylidene-D-fructose. 
