
%0 Journal Article
%A Brown, DJ 
%A Lyall, JM 
%T Pyrimidine reactions. XI. Amination rates for two chlorodimethylprimidines without solvent
%J Australian Journal of Chemistry
%D 1965/11/01
%V 18
%N 11
%P 1811-1817
%K 
%R https://doi.org/10.1071/CH9651811
%U https://www.publish.csiro.au/paper/CH9651811 
%X Second-order rate constants, Arrhenius parameters, and isokinetic temperatures are presented for the reactions of 2-chloro-4,6-dimethylpyrimidine and 4-chloro-2,6-dimethylpyrimidine with some n-alkyl-, branched alkyl-, and dialkylamines in the absence of a solvent. The differences between these values and those available for the same reactions in a solvent are briefly discussed. An equation is derived for satisfactorily converting the apparent first-order rate constants previously reported by us into second-order rate constants. 
