
TY  - JOUR
A1  - Bottomley, GA 
A1  - Nyberg, GL 
T1  - Reactions with half-lives of several years
JF  - Australian Journal of Chemistry
JO  - Aust. J. Chem.
Y1  - 1964
VL  - 17
IS  - 4
SP  - 406
EP  - 410
KW  - 
UR  - https://doi.org/10.1071/CH9640406 
N2  - The gas-phase thermal decomposition of dimethyldiazirine, (CH3)2CN2, at very slow rates has been investigated using precision gas-volumetric techniques previously applied to second virial coefficient studies. At 50-70° the first-order kinetics correspond to half-lives about 0.3-3.0 years. The present results, together with data obtained by other workers using conventional apparatus at 124-174°, fit a single log rate-reciprocal temperature activation energy equation. 
ER  -

