
TY  - JOUR
A1  - Dwyer, FP 
A1  - Goodwin, HA 
A1  - Gyarfas, EC 
T1  - Mono- and Bis-(2,2'-bipyridine) and -(1,10-phenanthroline) Chelates of Ruthenium and Osmium. II. Bischelates of Bivalent and Tervalent Ruthenium
JF  - Australian Journal of Chemistry
JO  - Aust. J. Chem.
Y1  - 1963
VL  - 16
IS  - 4
SP  - 544
EP  - 548
KW  - 
UR  - https://doi.org/10.1071/CH9630544 
N2  - Bis(phenanthro1ine) and bis(bipyridine)ruthenium(~~) chelates have been prepared by the pyrolysis, at 300°C, of phenanthrolinium tetrachlorophenanthrolineruthenate(III) and bipyridinium tetrachlorobipyridineruthenate(III). In the complexes [RuB2Cl2] the chelating base molecules are firmly bound but the chlorine atoms are replaceable by a variety of ligands such as water, pyridine, or acetylacetone. The complexes are spin-paired and show no tendency to disproportionation to the tris complexes, under normal experimental conditions. 
ER  -

