
TY  - JOUR
A1  - Sutton, GJ 
T1  - Some Studies in Inorganic Complexes. XIV. Reactions of 2-Methyl-6-aminopyridine and 2-Thioamidopyridine with Some Transition Metal Ions
JF  - Australian Journal of Chemistry
JO  - Aust. J. Chem.
Y1  - 1963
VL  - 16
IS  - 3
SP  - 371
EP  - 375
KW  - 
UR  - https://doi.org/10.1071/CH9630371 
N2  - The following complexes of the chelating ligands 2-methyl-6-aminomethylpyridine (6-methyl-2-picolylamine or mepic) and 2-thioamidopyridine (thiopic) have been prepared and studied: [Cu mepic2X]X, where X = Cl, Br, I, NO3, ClO4, [Cu mepic2C2O4], [Ni mepic3][ClO4]2, [M(II) thiopic3][ClO4]2, [M(III) thiopic3][ClO4]3, (M(II) = Co, Ni; M(III) = CO, Fe), and [Co thiopic3]Cl2. Conductance measurements in ethanol, nitromethane, and nitrobenzene indicate that the [Cu mepic2X]X complexes are 5-covalent whilst the other complexes studied are 6-covalent. All the complexes are &quot;spin free&quot; excepting those of Co(III). Absorption spectra of the copper complexes in the near ultraviolet region were also made. 
ER  -

