
TY  - JOUR
A1  - Jenkins, FE 
A1  - Hambly, AN 
T1  - Solvolysis of Sulphonyl Halides. II. The Alcoholysis of Aromatic Sulphonyl Chlorides in Ethanol-Acetone and Methanol-Acetone
JF  - Australian Journal of Chemistry
JO  - Aust. J. Chem.
Y1  - 1961
VL  - 14
IS  - 2
SP  - 205
EP  - 210
KW  - 
UR  - https://doi.org/10.1071/CH9610205 
N2  - The solvolysis of aromatic sulphonyl chlorides in methanol-acetone and ethanol-acetone shows only small, irregular effects due to para-substituents because the experimental temperature range is close to the isokinetic temperature. The modification of reaction conditions in SN2 substitutions, so that the isokinetic condition is brought into the experimental temperature range, is discussed.   Rates for methanolysis are lower than those for hydrolysis and are about four times the rates for the corresponding ethanolysis reactions. 
ER  -

