
%0 Journal Article
%A Brown, RD 
%A Heffernan, ML 
%T The Variable Electronegativity Method. VII. Pyrazole, Its Anion and Cation
%J Australian Journal of Chemistry
%D 1960/03/01
%V 13
%N 1
%P 49-57
%K 
%R https://doi.org/10.1071/CH9600049
%U https://www.publish.csiro.au/paper/CH9600049 
%X Results of a VESCF treatment of pyrazole, its anion, and cation are reported. A comparison is made of the chemical properties of pyrazole and those predicted from the calculated &#960;-electron densities. An ambiguity in the comparison owing to the rapid tautomerization of pyrazole is emphasized. The calculated &#960;-electron distribution in the anion supports the suggestion made in previous papers that the relative electronegativities of carbon and tertiary nitrogen reverse when their &#960;-electron densities exceed 1.2.   The dipole moment is predicted to be about 2.5 D for pyrazole, in agreement with observations in solution. Theoretical values of ionization potentials are also presented.   An analysis is made of VESCF matrix elements and some empirical guides as to suitable values of coulomb and resonance parameters for five-membered ring nitrogen heterocycles are suggested. 
