
TY  - JOUR
A1  - Ingles, DL 
T1  - Chemistry of Non-Enzymic Browning. VIII. The Hydrolytic reactions of Aldose Bisulphite addition compounds
JF  - Australian Journal of Chemistry
JO  - Aust. J. Chem.
Y1  - 1959
VL  - 12
IS  - 2
SP  - 288
EP  - 295
KW  - 
UR  - https://doi.org/10.1071/CH9590288 
N2  - A study has been made of the hydrolytic reactions of aldose bisulphite addition compounds (Ingles 1959a, 19596). Addition compounds which had a hydroxyl group at C1 were stable in 10 per cent, acetic acid but decomposed in water and sodium hydroxide forming the a-form of the parent D-aldose. Compounds in which the hydroxyl at C1 was replaced by an amine group were unstable in water, 10 per cent. acetic acid, and sodium hydroxide. In the last solvent breakdown to the &#945;-form of the D-glycosylamine was observed.   Decomposition in sodium hydroxide appears to occur with inversion of configuration at C1. The configurations at C1 of the bisulphite addition compounds have been listed. 
ER  -

