
TY  - JOUR
A1  - Higgins, HG 
T1  - Rapidreaction between unifunctional molecules and molecules unifunctional at one position and n-functional at another
JF  - Australian Journal of Chemistry
JO  - Aust. J. Chem.
Y1  - 1957
VL  - 10
IS  - 2
SP  - 99
EP  - 111
KW  - 
UR  - https://doi.org/10.1071/CH9570099 
N2  - Rate equations for the reaction between A and B, where B is unifunctional, and A is unifunctional at one and n-functional at the other of two independent positions, lead to expressions for the final relative concentrations of the reactants and products in terms of the initial concentrations of A and B, the ratio of the velocity constants at the two positions on A, and the functionality n. These results are applied to the reaction of tryptophane with p-diazobenzenesulphonic acid, in which it appears that the indole group reacts somewhat faster than the amino group. 
ER  -

