
TY  - JOUR
A1  - Buchanan, GS 
A1  - Werner, RL 
T1  - Direct current polarography in the presence of alternating voltages. II. Irreversible systems
JF  - Australian Journal of Chemistry
JO  - Aust. J. Chem.
Y1  - 1954
VL  - 7
IS  - 4
SP  - 312
EP  - 318
KW  - 
UR  - https://doi.org/10.1071/CH9540312 
N2  - The superposition of a small alternating voltage on the normal D.C. voltage applied at the dropping mercury electrode (D.M.E.) results in the case of irreversible systems in a marked displacement of the entire D.C. wave, in contradistinction to those cases known to be reversible. Such a displacement has been interpreted in terms of an ionic picture.   The cases examined were ZnO2--, Fe++, Ni++, Sb+++ in the presence of varying concentrations of Cl-, and Cd++ in the presence of varying concentrations of cyclohexanol. The effect of frequency was investigated. 
ER  -

