
%0 Journal Article
%A Buchanan, GS 
%A Werner, RL 
%T Direct current polarography in the presence of alternating voltages. II. Irreversible systems
%J Australian Journal of Chemistry
%D 1954/12/01
%V 7
%N 4
%P 312-318
%K 
%R https://doi.org/10.1071/CH9540312
%U https://www.publish.csiro.au/paper/CH9540312 
%X The superposition of a small alternating voltage on the normal D.C. voltage applied at the dropping mercury electrode (D.M.E.) results in the case of irreversible systems in a marked displacement of the entire D.C. wave, in contradistinction to those cases known to be reversible. Such a displacement has been interpreted in terms of an ionic picture.   The cases examined were ZnO2--, Fe++, Ni++, Sb+++ in the presence of varying concentrations of Cl-, and Cd++ in the presence of varying concentrations of cyclohexanol. The effect of frequency was investigated. 
