
TY  - JOUR
A1  - Banwell, Martin G. 
A1  - Darmos, Penny 
A1  - Hockless, David C. R. 
T1  - Taxane Diterpene Synthesis Studies. Part 1: Chemoenzymatic and Enantiodivergent Routes to AB-ring Substructures of Taxoids and <emph type="2">ent</emph>-Taxoids
JF  - Australian Journal of Chemistry
JO  - Aust. J. Chem.
Y1  - 2004
VL  - 57
IS  - 1
SP  - 41
EP  - 52
KW  - anionic oxy-Cope rearrangement &#8212; cis-1,2-dihydrocatechols &#8212; Diels-Alder reactions &#8212; natural products &#8212; Taxinine
UR  - https://doi.org/10.1071/CH03164 
N2  - The microbially derived cis-1,2-dihydrocatechol 2 has been converted, via reaction sequences including Diels&#8211;Alder cycloaddition and anionic oxy-Cope rearrangement steps, into enantiopure bicyclo[5.3.1]undecenes 21 and 34, which correspond to AB-ring substructures of ent-taxoids and taxoids, respectively. 
ER  -

