
TY  - JOUR
A1  - Otter, Carl A. 
A1  - Hartshorn, Richard M. 
T1  - Preparation and Photochemistry of Some Cobalt(<emph type="6">III</emph>) Complexes of Tridentate Oxime-Diamine and Oxime-Amino Acid Ligands
JF  - Australian Journal of Chemistry
JO  - Aust. J. Chem.
Y1  - 2003
VL  - 56
IS  - 12
SP  - 1179
EP  - 1186
KW  - 
UR  - https://doi.org/10.1071/CH03092 
N2  - Cobalt(III) complexes of tridentate ligands containing oxime-diamine and oxime-amino acid donor sets have been prepared, both by reduction of the related imine complexes. Many of the complexes have been characterized by X-ray crystallographic techniques. The photochemistry of these complexes has been studied. The oxime-diamine systems are rather unreactive, undergoing slow isomerization before decomposition. The oxime-amino acid systems appear to undergo decarboxylation reactions. Photolyses of tetrachlorozincate salts of some of the complexes result in binuclear species in which a trichlorozinc moiety is bound to the cobalt species through an oxime oxygen atom. 
ER  -

