
TY  - JOUR
A1  - Khandar, Ali Akbar 
A1  - Hosseini-Yazdi, Seyed Abolfazl 
T1  - Synthesis and Characterization of the Nickel(<emph type="6">II</emph>) Complex of a Macrocyclic Schiff Base Ligand with a Single Pendant Coordinating Hydroxyl Arm
JF  - Australian Journal of Chemistry
JO  - Aust. J. Chem.
Y1  - 2003
VL  - 56
IS  - 12
SP  - 1255
EP  - 1257
KW  - 
UR  - https://doi.org/10.1071/CH03071 
N2  - The synthesis and characterization of a nickel(II) complex of the ligand 8,9,18,19-tetrahydro-7H,17H-dibenzo[f,o][1,5,9,13]dioxadiazacyclohexadecin-18-ol (L) is described. Complex [NiL(NO3)]NO3 was prepared by facile template reaction of the appropriate dialdehyde 2-(3-(2-formylphenoxy)-2-hydroxypropoxy)benzaldehyde (1) and 1,3-diaminopropane in the presence of nickel nitrate. X-Ray crystallography indicated that the compound was a six-coordinate complex that contained a pentadentate ligand and an NO3&minus; anion trans to the alcoholic donor. The blue complex contains nickel(II) in a distorted octahedral environment of N2O4 donors, and crystallizes in the monoclinic space group C2/c with a 26.921(10), b 9.075(2), c 21.193(7) &#197;, &#946; 122.12(2)&#176;, and Z 8. From spectro-scopic and conductivity studies of the complex it has been found that six-coordinate [NiL(NO3)]+ cations and NO3&minus; anions are formed in solution. 
ER  -

