
TY  - JOUR
A1  - Blackman, A. G. 
T1  - Synthesis and Structure of the Methylated Tren Derivative <emph type="2">N</emph>,<emph type="2">N</emph>,<emph type="2">N</emph>-Tris(2-aminoethyl)-<emph type="2">N</emph>-methylammonium Chloride Trihydrochloride
JF  - Australian Journal of Chemistry
JO  - Aust. J. Chem.
Y1  - 2002
VL  - 55
IS  - 4
SP  - 263
EP  - 266
KW  - 
UR  - https://doi.org/10.1071/CH02060 
N2  - The synthesis and X-ray crystal structure of the new tren derivative N,N,N-tris(2-aminoethyl)-N-methylammonium chloride trihydrochloride are detailed. The compound was synthesized by methylation of tris(2-phthalimido-ethyl)amine using dimethyl sulfate followed by acid deprotection. N,N,N-Tris(2-aminoethyl)-N-methylammonium chloride trihydrochloride crystallizes in the hexagonal space group P63 and the X-ray crystal structure reveals one-dimensional chains of cations extensively hydrogen-bonded to two different types of chloride counter ions, one of which exhibits a coordination number of nine. The cation is a poor ligand towards both CoIII and NiII. 
ER  -

