
%0 Journal Article
%A Baker, Murray V. 
%A Palermo, Maria C. 
%A Skelton, Brian W. 
%A White, Allan H. 
%T Titanium(<emph type="6">IV</emph>) Imido Complexes of 1,3,5-Trialkyl-1,3,5-triazacyclohexanes
%J Australian Journal of Chemistry
%D 1999/04/16
%V 52
%N 3
%P 179-184
%K 
%R https://doi.org/10.1071/C98173
%U https://www.publish.csiro.au/paper/C98173 
%X Reactions of the imido complex Ti(NBut)Cl2(py)3 (py = pyridine) with 1,3,5-trialkyl-1,3,5-triazacyclo- hexanes (R3tach) produce the corresponding imido complexes TiCl2(NBut)(R3tach) (R = Et, But). The new complexes have been characterized by n.m.r. spectroscopy and, for the R = Bu t case, by X-ray diffraction studies. The absence of a C3v axis of symmetry for the new complexes allowed complete and unequivocal assignment of their 1H n.m.r. spectra by consideration of proton&#123;proton coupling and nuclear Overhauser effects. 
