
TY  - JOUR
A1  - Khalafy, Jabbar 
A1  - Prager, Rolf H 
T1  - Flash Vacuum Pyrolysis of Some <emph type="2">N</emph>-Benzylbenzotriazoles and <emph type="2">N</emph>-Benzylbenzisoxazolones
JF  - Australian Journal of Chemistry
JO  - Aust. J. Chem.
Y1  - 1998
VL  - 51
IS  - 10
SP  - 925
EP  - 930
KW  - 
UR  - https://doi.org/10.1071/C98065 
N2  - The flash vacuum pyrolysis products of 2-(benzotriazol-1-ylmethyl)benzonitrile, methyl 2-(benzotriazol-1-ylmethyl)benzoate and the corresponding benzisoxazolones have been characterized. The benzotriazoles lose nitrogen to give diradicals which undergo intramolecular hydrogen-atom transfer or cyclization, while the benzisoxazolones rearrange initially to the corresponding benzaldehyde N-(2-carboxyphenyl)imines which undergo subsequent intramolecular addition reactions. 
ER  -

